Msds Jotun Thinner 17 12r12
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SUPPLIED BY SML PROTECTIVE COATINGS - TEL: 01285 862 132 - WEB: WWW.SMLPROTECTIVECOATINGS.CO.UK
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010
SAFETY DATA SHEET Jotun Thinner No. 17 SECTION 1: Identification of the substance/mixture and of the company/ undertaking 1.1 Product identifier Product name
: Jotun Thinner No. 17
Product code
: 553
Product description
: Solvent.
Product type
: Liquid.
Other means of identification
: Not available.
1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses Uses in Coatings - Industrial use Uses in Coatings - Professional use Uses in Coatings - Consumer use: Apply this product only as specified on the label. Consumer applications, Industrial applications, Professional applications, Used by spraying.
See Annex to the Safety data sheet for additional information in the Exposure Scenario(s). 1.3 Details of the supplier of the safety data sheet Jotun Paints (Europe) Ltd. Stather Road Flixborough, Scunthorpe North Lincolnshire DN15 8RR England Tel: +44 17 24 40 00 00 Fax: +44 17 24 40 01 00 [email protected] 1.4 Emergency telephone number NHS; phone 111. 553
Coatings: Solvent-borne.
553
1,2,5
^(ValidationDate).
1
SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Product definition
: Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] Flam. Liq. 3, H226 Skin Irrit. 2, H315 Eye Dam. 1, H318 STOT SE 3, H335 STOT SE 3, H336 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 Classification according to Directive 1999/45/EC [DPD] The product is classified as dangerous according to Directive 1999/45/EC and its amendments. Classification : R10 Xn; R20/21, R65 Xi; R41, R37/38 N; R51/53 Physical/chemical : Flammable. hazards Date of issue
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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) Jotun Thinner No. 17
SECTION 2: Hazards identification Human health hazards
: Harmful by inhalation and in with skin. Harmful: may cause lung damage if swallowed. Risk of serious damage to eyes. Irritating to respiratory system and skin. Environmental hazards : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. See Section 16 for the full text of the R phrases or H statements declared above. See Section 11 for more detailed information on health effects and symptoms. 2.2 Label elements Hazard pictograms
:
Signal word
: Danger.
Hazard statements
: Flammable liquid and vapour. Causes serious eye damage. Causes skin irritation. May be fatal if swallowed and enters airways. May cause respiratory irritation. May cause drowsiness or dizziness. Toxic to aquatic life with long lasting effects.
Precautionary statements General
: Keep out of reach of children.
Prevention
: Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use only outdoors or in a well-ventilated area. Avoid release to the environment. : IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF IN EYES: Immediately call a POISON CENTER or physician. : Keep cool.
Response Storage Disposal Hazardous ingredients
Supplemental label elements Additional information
: Dispose of contents and container in accordance with all local, regional, national and international regulations. : Solvent naphtha (petroleum), light arom. (<0.1% Benzene) xylene butan-1-ol : Not applicable. : Not applicable.
2.3 Other hazards Other hazards which do not result in classification
: None known.
SECTION 3: Composition/information on ingredients Substance/mixture
: Mixture Classification
Product/ingredient name
Date of issue
Identifiers
%
67/548/EEC
Regulation (EC) No. 1272/2008 [CLP]
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Type
Notes
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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) Jotun Thinner No. 17
SECTION 3: Composition/information on ingredients Solvent naphtha (petroleum), light arom. (<0.1% Benzene)
REACH #: 01-2119455851-35 EC: 265-199-0 CAS: 64742-95-6
≥50 <75
xylene
REACH #: 01-2119488216-32 EC: 215-535-7 CAS: 1330-20-7 Index: 601-022-00-9 REACH #: 01-2119484630-38 EC: 200-751-6 CAS: 71-36-3 Index: 603-004-00-6
≥10 <25
REACH #: 01-2119489370-35 EC: 202-849-4 CAS: 100-41-4
≥3 <5
butan-1-ol
ethylbenzene
Index: 601-023-00-4
R10
Flam. Liq. 3, H226
[1] [2]
H-P
Xn; R65 Xi; R37 R66, R67 N; R51/53
STOT SE 3, H335 STOT SE 3, H336 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 Flam. Liq. 3, H226
[1] [2]
C
Acute Tox. 4, H312 Acute Tox. 4, H332 Skin Irrit. 2, H315 Flam. Liq. 3, H226
[1] [2]
-
Acute Tox. 4, H302 Skin Irrit. 2, H315 Eye Dam. 1, H318 STOT SE 3, H335 STOT SE 3, H336 Flam. Liq. 2, H225
[1] [2]
-
R10 Xn; R20/21 Xi; R38
≥10 <25
R10 Xn; R22 Xi; R41, R37/38 R67 F; R11
Xn; R20, R48/20, R65 Acute Tox. 4, H332 STOT RE 2, H373 (ears) Asp. Tox. 1, H304 See Section 16 for See Section 16 for the full text of the the full text of the H R-phrases declared statements above. declared above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment, are PBTs or vPvBs or have been assigned a workplace exposure limit and hence require reporting in this section. Type [1] Substance classified with a health or environmental hazard [2] Substance with a workplace exposure limit [3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII [4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII [5] Substance of equivalent concern Occupational exposure limits, if available, are listed in Section 8.
SECTION 4: First aid measures 4.1 Description of first aid measures General
Inhalation
Skin Eye
Ingestion Protection of first-aiders
Date of issue
: In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and seek medical advice. : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser. Do NOT use solvents or thinners. : Check for and remove any lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention. : If swallowed, seek medical advice immediately and show the container or label. Keep person warm and at rest. Do NOT induce vomiting. : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. : 23.03.2015.
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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) Jotun Thinner No. 17
SECTION 4: First aid measures 4.2 Most important symptoms and effects, both acute and delayed Potential acute health effects Eye
: Causes serious eye damage.
Inhalation
: Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. : Causes skin irritation.
Skin Ingestion
: Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Over-exposure signs/symptoms Eye : Adverse symptoms may include the following: pain watering redness Inhalation : Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness Skin : Adverse symptoms may include the following: pain or irritation redness blistering may occur Ingestion : Adverse symptoms may include the following: stomach pains nausea or vomiting 4.3 Indication of any immediate medical attention and special treatment needed Notes to physician
: Treat symptomatically. poison treatment specialist immediately if large quantities have been ingested or inhaled. : No specific treatment.
Specific treatments
SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media
: Recommended: alcohol-resistant foam, CO₂, powders, water spray.
Unsuitable extinguishing media
: Do not use water jet.
5.2 Special hazards arising from the substance or mixture Hazards from the substance or mixture
Hazardous thermal decomposition products
: Flammable liquid and vapour. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. : Decomposition products may include the following materials: carbon dioxide carbon monoxide
5.3 Advice for firefighters Special protective actions for fire-fighters
Date of issue
: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. : 23.03.2015.
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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) Jotun Thinner No. 17
SECTION 5: Firefighting measures Special protective equipment for fire-fighters
: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.
SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel
: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". 6.2 Environmental precautions
: Avoid dispersal of spilt material and runoff and with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage.
6.3 Methods and material for containment and cleaning up Small spill
: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product.
Large spill
6.4 Reference to other sections
: See Section 1 for emergency information. See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment information.
SECTION 7: Handling and storage The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). 7.1 Precautions for safe handling Prevent the creation of flammable or explosive concentrations of vapours in air and avoid vapour concentrations higher than the occupational exposure limits. In addition, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Mixture may charge electrostatically: always use earthing leads when transferring from one container to another. Operators should wear antistatic footwear and clothing and floors should be of the conducting type. Keep away from heat, sparks and flame. No sparking tools should be used. Avoid with skin and eyes. Avoid the inhalation of dust, particulates, spray or mist arising from the application of this mixture. Avoid inhalation of dust from sanding. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Put on appropriate personal protective equipment (see Section 8). Never use pressure to empty. Container is not a pressure vessel. Always keep in containers made from the same material as the original one. Date of issue
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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) Jotun Thinner No. 17
SECTION 7: Handling and storage Comply with the health and safety at work laws. Do not allow to enter drains or watercourses. Information on fire and explosion protection Vapours are heavier than air and may spread along floors. Vapours may form explosive mixtures with air. When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits. 7.2 Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Notes on t storage Keep away from: oxidising agents, strong alkalis, strong acids. Additional information on storage conditions Observe label precautions. Store in a dry, cool and well-ventilated area. Keep away from heat and direct sunlight. Keep away from sources of ignition. No smoking. Prevent unauthorised access. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. 7.3 Specific end use(s) Recommendations
: Not available.
Industrial sector specific solutions
: Not available.
SECTION 8: Exposure controls/personal protection The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). 8.1 Control parameters Occupational exposure limits Product/ingredient name Solvent naphtha (petroleum), light arom. (<0. 1% Benzene) xylene
butan-1-ol
ethylbenzene
Recommended monitoring procedures
Date of issue
Exposure limit values EH40-WEL (United Kingdom (UK), 12/2011). Absorbed through skin. TWA: 200 mg/m³ 8 hours. Form: All forms TWA: 40 ppm 8 hours. Form: All forms EH40/2005 WELs (United Kingdom (UK), 12/2011). Absorbed through skin. STEL: 441 mg/m³ 15 minutes. STEL: 100 ppm 15 minutes. TWA: 220 mg/m³ 8 hours. TWA: 50 ppm 8 hours. EH40/2005 WELs (United Kingdom (UK), 12/2011). Absorbed through skin. STEL: 154 mg/m³ 15 minutes. STEL: 50 ppm 15 minutes. EH40/2005 WELs (United Kingdom (UK), 12/2011). Absorbed through skin. STEL: 552 mg/m³ 15 minutes. STEL: 125 ppm 15 minutes. TWA: 100 ppm 8 hours. TWA: 441 mg/m³ 8 hours.
: If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of procedures : 23.03.2015.
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SECTION 8: Exposure controls/personal protection for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of hazardous substances will also be required. Derived no effect levels Product/ingredient name Solvent naphtha (petroleum), light arom. (<0.1% Benzene)
Type
Exposure
DNEL Long term Dermal DNEL Long term Inhalation DNEL Long term Dermal DNEL Long term Inhalation DNEL Long term Oral
xylene
DNEL Short term Inhalation DNEL Short term Inhalation DNEL Long term Dermal DNEL Long term Inhalation DNEL Long term Dermal DNEL Long term Inhalation DNEL Long term Oral
butan-1-ol
DNEL Long term Inhalation DNEL Long term Oral DNEL Long term Inhalation DNEL Short term Inhalation DNEL Long term Dermal
ethylbenzene
DNEL Long term Inhalation DNEL Long term Inhalation DNEL Long term Oral
Value
Population
Effects
25 mg/kg Workers bw/day 150 mg/m³ Workers
Systemic
11 mg/kg bw/day 32 mg/m³
Consumers
Systemic
Consumers
Systemic
11 mg/kg Consumers bw/day 289 mg/m³ Workers
Systemic
289 mg/m³ Workers
Local
180 mg/kg Workers bw/day 77 mg/m³ Workers
Systemic
108 mg/kg Consumers bw/day 14,8 mg/m³ Consumers
Systemic
1,6 mg/kg Consumers bw/day 310 mg/m³ Workers
Systemic
3,125 mg/ kg bw/day 55 mg/m³
Consumers
Systemic
Consumers
Local
Systemic
Systemic
Systemic
Systemic
Local
293 mg/m³ Workers
Local
180 mg/kg Workers bw/day 77 mg/m³ Workers
Systemic
15 mg/m³
Consumers
Systemic
1,6 mg/kg bw/day
Consumers
Systemic
Systemic
Predicted no effect concentrations Product/ingredient name xylene
butan-1-ol
ethylbenzene
Date of issue
Type
Compartment Detail
PNEC Fresh water PNEC Marine PNEC Sewage Treatment Plant PNEC Fresh water sediment PNEC Marine water sediment PNEC Soil PNEC Fresh water PNEC Marine PNEC Sewage Treatment Plant PNEC Fresh water sediment PNEC Marine water sediment PNEC Soil PNEC Fresh water PNEC Marine PNEC Sewage Treatment
Value
Method Detail
0,327 mg/l 0,327 mg/l 6,58 mg/l
-
12,46 mg/kg dwt 12,46 mg/kg dwt 2,31 mg/kg dwt 0,082 mg/l 0,0082 mg/l 2476 mg/l
-
0,178 mg/kg dwt 0,0178 mg/kg dwt 0,015 mg/kg dwt 0,1 mg/l 0,01 mg/l 9,6 mg/l
-
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SECTION 8: Exposure controls/personal protection Plant PNEC Fresh water sediment PNEC Soil PNEC Secondary Poisoning
13,7 mg/kg dwt 2,68 mg/kg dwt 20 mg/kg
-
8.2 Exposure controls Appropriate engineering controls
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Individual protection measures Hygiene measures
Eye/face protection
: Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead.
Skin protection Hand protection
: There is no one glove material or combination of materials that will give unlimited resistance to any individual or combination of chemicals. The breakthrough time must be greater than the end use time of the product. The instructions and information provided by the glove manufacturer on use, storage, maintenance and replacement must be followed. Gloves should be replaced regularly and if there is any sign of damage to the glove material. Always ensure that gloves are free from defects and that they are stored and used correctly. The performance or effectiveness of the glove may be reduced by physical/ chemical damage and poor maintenance. Barrier creams may help to protect the exposed areas of the skin but should not be applied once exposure has occurred. May be used, gloves(breakthrough time) 4 - 8 hours: neoprene, butyl rubber, Viton®, Barricade, F 3, Responder, PVC Not recommended, gloves(breakthrough time) < 1 hour: PE Recommended, gloves(breakthrough time) > 8 hours: 4H, Teflon, nitrile rubber, polyvinyl alcohol (PVA)
Body protection
Other skin protection
Date of issue
For right choice of glove materials, with focus on chemical resistance and time of penetration, seek advice by the supplier of chemical resistant gloves. The must check that the final choice of type of glove selected for handling this product is the most appropriate and takes into the particular conditions of use, as included in the 's risk assessment. : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Refer to European Standard EN 1149 for further information on material and design requirements and test methods. : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
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SECTION 8: Exposure controls/personal protection Respiratory protection
Environmental exposure controls
: If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use respiratory mask with charcoal and dust filter when spraying this product.(as filter combination A2-P2). In confined spaces, use compressed-air or fresh-air respiratory equipment. When use of roller or brush, consider use of charcoalfilter. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance Physical state
: Liquid.
Colour Odour Odour threshold
: Clear. : Characteristic. : Not available.
pH Melting point/freezing point
: Not applicable. : Not applicable.
Initial boiling point and boiling range
: Lowest known value: 117°C (242.6°F) (butan-1-ol). Weighted average: 130. 33°C (266.6°F)
Flash point
: Closed cup: 25°C
Evaporation rate
: Highest known value: 0.84 (ethylbenzene) Weighted average: 0.65compared with butyl acetate : Not applicable.
Flammability (solid, gas) Burning time Burning rate
: Not applicable. : Not applicable.
Upper/lower flammability or explosive limits
: 1.1 - 11.3%
Vapour pressure Vapour density Relative density
: Highest known value: 1.2 kPa (9.3 mm Hg) (at 20°C) (ethylbenzene). Weighted average: 0.72 kPa (5.4 mm Hg) (at 20°C) : Highest known value: 3.7 (Air = 1) (xylene). Weighted average: 3.29 (Air = 1) : 0.86 g/cm³
Solubility(ies)
: Insoluble in the following materials: cold water and hot water.
Partition coefficient: n-octanol/ : Not available. water Auto-ignition temperature Decomposition temperature Viscosity
Explosive properties Oxidising properties
: Lowest known value: 280 to 470°C (536 to 878°F) (Solvent naphtha (petroleum), light aromatic ). : Not available. : Dynamic: Highest known value: 2.947 (butan-1-ol) Weighted average: 1.57 Kinematic: Highest known value: 0.773 cSt (ethylbenzene) Kinematic (40C): Highest known value: 0.4 to 0.9 cSt (Solvent naphtha (petroleum), light aromatic ) Weighted average: 0.65 cSt : Not available. : Not available.
9.2 Other information No additional information.
Date of issue
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SECTION 10: Stability and reactivity 10.1 Reactivity
: No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability
: The product is stable.
10.3 Possibility of hazardous reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
10.4 Conditions to avoid
: Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. : Reactive or incompatible with the following materials: oxidizing materials : Under normal conditions of storage and use, hazardous decomposition products should not be produced.
10.5 Incompatible materials 10.6 Hazardous decomposition products
SECTION 11: Toxicological information 11.1 Information on toxicological effects There are no data available on the mixture itself. The mixture has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. See Sections 2 and 15 for details. Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by absorption through the skin. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness. Repeated or prolonged with the mixture may cause removal of natural fat from the skin, resulting in non-allergic dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversible damage. Swallowing may cause nausea, diarrhoea, vomiting, gastro-intestinal irritation and chemical pneumonia. Aspiration hazard if swallowed. Can enter lungs and cause damage. Risk of serious damage to eyes. Product/ingredient name xylene
Result LC50 Inhalation Gas. LD50 Oral LC50 Inhalation Gas. LD50 Dermal LD50 Oral
ethylbenzene
Species Rat Rat Rabbit Rabbit Rat
Dose 6700 ppm 4300 mg/kg 4000 ppm >5000 mg/kg 3500 mg/kg
Exposure 4 hours 4 hours -
Acute toxicity estimates Route
ATE value
Oral Dermal Inhalation (vapours)
3333,3 mg/kg 5301,2 mg/kg 44 mg/l
Specific target organ toxicity (single exposure) Product/ingredient name
Category
Route of exposure
Solvent naphtha (petroleum), light arom. (<0.1% Benzene) Category 3
Not applicable.
butan-1-ol
Not applicable.
Category 3
Target organs Respiratory tract irritation and Narcotic effects Respiratory tract irritation and Narcotic effects
Specific target organ toxicity (repeated exposure) Product/ingredient name ethylbenzene
Category Category 2
Route of exposure Not determined
Target organs ears
Aspiration hazard Product/ingredient name Solvent naphtha (petroleum), light arom. (<0.1% Benzene) ethylbenzene
Date of issue
Result ASPIRATION HAZARD - Category 1 ASPIRATION HAZARD - Category 1
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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) Jotun Thinner No. 17
SECTION 11: Toxicological information SECTION 12: Ecological information 12.1 Toxicity Product/ingredient name
Result
Solvent naphtha (petroleum), Acute EC50 <10 mg/l light arom. (<0.1% Benzene) Acute IC50 <10 mg/l Acute LC50 <10 mg/l ethylbenzene Acute EC50 7,2 mg/l Acute EC50 2,93 mg/l Acute LC50 4,2 mg/l Conclusion/Summary
Species
Exposure
Daphnia
48 hours
Algae Fish Algae Daphnia Fish
72 hours 96 hours 48 hours 48 hours 96 hours
: Water polluting material. May be harmful to the environment if released in large quantities. This material is toxic to aquatic life with long lasting effects.
12.2 Persistence and degradability Conclusion/Summary
: Not available.
Product/ingredient name
Aquatic half-life
Solvent naphtha (petroleum), light arom. (<0.1% Benzene) xylene ethylbenzene -
Photolysis
Biodegradability
-
Not readily
-
Readily Readily
12.3 Bioaccumulative potential Product/ingredient name
LogPow
BCF
Potential
Solvent naphtha (petroleum), light arom. (<0.1% Benzene) xylene butan-1-ol ethylbenzene
-
10 to 2500
high
3,12 0,88 3,15
8.1 to 25.9 -
low low low
12.4 Mobility in soil Soil/water partition coefficient (KOC)
: Not available.
Mobility
: Not available.
12.5 Results of PBT and vPvB assessment PBT
: Not applicable.
vPvB
: Not applicable.
12.6 Other adverse effects
: No known significant effects or critical hazards.
SECTION 13: Disposal considerations The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). 13.1 Waste treatment methods Do not allow to enter drains or watercourses. Material and/or container must be disposed of as hazardous waste. European waste catalogue : 08 01 11* Waste paint and varnish containing organic solvents or other dangerous substances If this product is mixed with other wastes, this code may no longer apply. (EWC) If mixed with other wastes, the appropriate code should be assigned. For further information, your local waste authority.
Date of issue
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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) Jotun Thinner No. 17
SECTION 14: Transport information Transport within ’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Transport in accordance with ADR/RID, IMDG/IMO and ICAO/IATA and national regulation. International transport regulations 14.1 UN number
: 1263
14.2 UN proper shipping name
: Paint related material. Marine pollutant (Solvent naphtha (petroleum), light aromatic )
14.3 Transport hazard class(es)
: 3
Marking
: The environmental hazardous / marine pollutant mark is only applicable for packages containing more than 5 litres for liquids and 5 kg for solids. : III
14.4 Packing group 14.5 Environmental hazards
: Yes.
14.6 Special precautions for
: Transport within ’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Additional information ADR / RID
: Tunnel restriction code: (D/E) Hazard identification number: 30 Special provisions: 640E : The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.
IMDG
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Emergency schedules (EmS) F-E, S-E : Not available.
SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorisation Substances of very high concern None of the components are listed. Annex XVII - Restrictions : Not applicable. on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles Other EU regulations Europe inventory
: All components are listed or exempted.
Black List Chemicals
: Not listed
Priority List Chemicals
: Not listed
Integrated pollution prevention and control list (IPPC) - Air
: Not listed
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SECTION 15: Regulatory information Integrated pollution prevention and control list (IPPC) - Water
: Not listed
Chemical Weapons Convention List Schedule I Chemicals
: Not listed
Chemical Weapons Convention List Schedule II Chemicals
: Not listed
Chemical Weapons Convention List Schedule III Chemicals
: Not listed
15.2 Chemical Safety Assessment
: This product contains substances for which Chemical Safety Assessments are still required.
SECTION 16: Other information Indicates information that has changed from previously issued version. Abbreviations and : ATE = Acute Toxicity Estimate CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. acronyms 1272/2008] DNEL = Derived No Effect Level EUH statement = CLP-specific Hazard statement PNEC = Predicted No Effect Concentration RRN = REACH Registration Number Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] Classification
Justification
Flam. Liq. 3, H226 Skin Irrit. 2, H315 Eye Dam. 1, H318 STOT SE 3, H335 STOT SE 3, H336 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 Full text of abbreviated H statements
On basis of test data Calculation method Calculation method Calculation method Calculation method Expert judgment Calculation method : H225 H226 H302 (oral) H304 H312 (dermal) H315 H318 H332
Highly flammable liquid and vapour. Flammable liquid and vapour. Harmful if swallowed. May be fatal if swallowed and enters airways. Harmful in with skin. Causes skin irritation. Causes serious eye damage. Harmful if inhaled.
(inhalation)
Full text of classifications [CLP/GHS]
Date of issue
H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H373 May cause damage to organs through prolonged or repeated exposure. (ears) (ears) H411 Toxic to aquatic life with long lasting effects. : Acute Tox. 4, H302 ACUTE TOXICITY (oral) - Category 4 Acute Tox. 4, H312 ACUTE TOXICITY (dermal) - Category 4 Acute Tox. 4, H332 ACUTE TOXICITY (inhalation) - Category 4 Aquatic Chronic 2, H411 LONG-TERM AQUATIC HAZARD - Category 2 Asp. Tox. 1, H304 ASPIRATION HAZARD - Category 1 Eye Dam. 1, H318 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 Flam. Liq. 2, H225 FLAMMABLE LIQUIDS - Category 2 Flam. Liq. 3, H226 FLAMMABLE LIQUIDS - Category 3 Skin Irrit. 2, H315 SKIN CORROSION/IRRITATION - Category 2 STOT RE 2, H373 (ears) SPECIFIC TARGET ORGAN TOXICITY (REPEATED : 23.03.2015.
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SECTION 16: Other information STOT SE 3, H335 STOT SE 3, H336 Full text of abbreviated R phrases
Full text of classifications [DSD/DPD]
Date of printing
EXPOSURE) (ears) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
: R11- Highly flammable. R10- Flammable. R20- Harmful by inhalation. R22- Harmful if swallowed. R20/21- Harmful by inhalation and in with skin. R48/20- Harmful: danger of serious damage to health by prolonged exposure through inhalation. R65- Harmful: may cause lung damage if swallowed. R41- Risk of serious damage to eyes. R37- Irritating to respiratory system. R38- Irritating to skin. R37/38- Irritating to respiratory system and skin. R66- Repeated exposure may cause skin dryness or cracking. R67- Vapours may cause drowsiness and dizziness. R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. : F - Highly flammable Xn - Harmful Xi - Irritant N - Dangerous for the environment : 23.03.2015.
Date of issue/ Date of revision
: 23.03.2015.
Date of previous issue
: 09.12.2014.
Version
: 4.01
Notice to reader The information in this document is given to the best of Jotun's knowledge, based on laboratory testing and practical experience. Jotun's products are considered as semi-finished goods and as such, products are often used under conditions beyond Jotun's control. Jotun cannot guarantee anything but the quality of the product itself. Minor product variations may be implemented in order to comply with local requirements. Jotun reserves the right to change the given data without further notice. s should always consult Jotun for specific guidance on the general suitability of this product for their needs and specific application practices. If there is any inconsistency between different language issues of this document, the English (United Kingdom) version will prevail.
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Annex Jotun Thinner No. 17 Exposure Scenario: Uses in Coatings Sector of Use
: Industrial use
Process Category
: PROC05 PROC08a
Environmental release category(ies)
: ERC4
Industrial use
Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including product transfer and preparation, application by brush, spray by hand or similar methods) and equipment cleaning.
Operational conditions and risk management measures Control of worker exposure Frequency and duration of use
: Covers daily exposures up to 8 hours (unless stated differently)
General - Operational conditions
: Assumes use at not more than 20°C above ambient temperature, unless stated differently. Assumes a good basic standard of occupational hygiene is implemented
General - Risk management measures
: Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. Wear suitable coveralls to prevent exposure to the skin. Use suitable eye protection. See Section 8 for information on appropriate personal protective equipment.
Type of activity or process Preparation of material for application
Risk management measures : Provide a good standard of controlled ventilation (10 to 15 air changes per hour).
Control of environmental exposure Organisational measures to prevent/limit release from site
: Prevent environmental discharge consistent with regulatory requirements.
Conditions and measures related to external treatment of waste for disposal
: External treatment and disposal of waste should comply with applicable local and/or national regulations. See Section 13 for additional waste treatment information.
Conditions and measures related to external recovery of waste
: External recovery and recycling of waste should comply with applicable local and/or national regulations.
Additional information The exposure scenario for the mixture is based on the following substances: REACH #: 01-2119488216-32
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Annex Jotun Thinner No. 17 Exposure Scenario: Uses in Coatings Sector of Use
: Professional use
Process Category
: PROC05 PROC08a
Environmental release category(ies)
: ERC8a ERC8d
Professional use
Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including product transfer and preparation, application by brush, spray by hand or similar methods) and equipment cleaning.
Operational conditions and risk management measures Control of worker exposure Frequency and duration of use
: Covers daily exposures up to 8 hours (unless stated differently)
General - Operational conditions
: Assumes use at not more than 20°C above ambient temperature, unless stated differently. Assumes a good basic standard of occupational hygiene is implemented
General - Risk management measures
: Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. Wear suitable coveralls to prevent exposure to the skin. Use suitable eye protection. See Section 8 for information on appropriate personal protective equipment.
Type of activity or process
Risk management measures
Preparation of material for application Indoor
: Provide a good standard of controlled ventilation (10 to 15 air changes per hour). Avoid carrying out activities involving exposure for more than 1 hour. or Provide a good standard of controlled ventilation (10 to 15 air changes per hour). Wear a respirator conforming to EN140 with type A/P2 filter or better.
Preparation of material for application Outdoor
: Ensure operation is undertaken outdoors. Avoid carrying out activities involving exposure for more than 1 hour. or Ensure operation is undertaken outdoors. Wear a respirator conforming to EN140 with type A/P2 filter or better.
Control of environmental exposure Organisational measures to prevent/limit release from site
: Prevent environmental discharge consistent with regulatory requirements.
Conditions and measures related to external treatment of waste for disposal
: External treatment and disposal of waste should comply with applicable local and/or national regulations. See Section 13 for additional waste treatment information.
Conditions and measures related to external recovery of waste
: External recovery and recycling of waste should comply with applicable local and/or national regulations.
Additional information The exposure scenario for the mixture is based on the following substances: REACH #: 01-2119488216-32
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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010
SAFETY DATA SHEET Jotun Thinner No. 17 SECTION 1: Identification of the substance/mixture and of the company/ undertaking 1.1 Product identifier Product name
: Jotun Thinner No. 17
Product code
: 553
Product description
: Solvent.
Product type
: Liquid.
Other means of identification
: Not available.
1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses Uses in Coatings - Industrial use Uses in Coatings - Professional use Uses in Coatings - Consumer use: Apply this product only as specified on the label. Consumer applications, Industrial applications, Professional applications, Used by spraying.
See Annex to the Safety data sheet for additional information in the Exposure Scenario(s). 1.3 Details of the supplier of the safety data sheet Jotun Paints (Europe) Ltd. Stather Road Flixborough, Scunthorpe North Lincolnshire DN15 8RR England Tel: +44 17 24 40 00 00 Fax: +44 17 24 40 01 00 [email protected] 1.4 Emergency telephone number NHS; phone 111. 553
Coatings: Solvent-borne.
553
1,2,5
^(ValidationDate).
1
SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Product definition
: Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] Flam. Liq. 3, H226 Skin Irrit. 2, H315 Eye Dam. 1, H318 STOT SE 3, H335 STOT SE 3, H336 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 Classification according to Directive 1999/45/EC [DPD] The product is classified as dangerous according to Directive 1999/45/EC and its amendments. Classification : R10 Xn; R20/21, R65 Xi; R41, R37/38 N; R51/53 Physical/chemical : Flammable. hazards Date of issue
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SECTION 2: Hazards identification Human health hazards
: Harmful by inhalation and in with skin. Harmful: may cause lung damage if swallowed. Risk of serious damage to eyes. Irritating to respiratory system and skin. Environmental hazards : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. See Section 16 for the full text of the R phrases or H statements declared above. See Section 11 for more detailed information on health effects and symptoms. 2.2 Label elements Hazard pictograms
:
Signal word
: Danger.
Hazard statements
: Flammable liquid and vapour. Causes serious eye damage. Causes skin irritation. May be fatal if swallowed and enters airways. May cause respiratory irritation. May cause drowsiness or dizziness. Toxic to aquatic life with long lasting effects.
Precautionary statements General
: Keep out of reach of children.
Prevention
: Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use only outdoors or in a well-ventilated area. Avoid release to the environment. : IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF IN EYES: Immediately call a POISON CENTER or physician. : Keep cool.
Response Storage Disposal Hazardous ingredients
Supplemental label elements Additional information
: Dispose of contents and container in accordance with all local, regional, national and international regulations. : Solvent naphtha (petroleum), light arom. (<0.1% Benzene) xylene butan-1-ol : Not applicable. : Not applicable.
2.3 Other hazards Other hazards which do not result in classification
: None known.
SECTION 3: Composition/information on ingredients Substance/mixture
: Mixture Classification
Product/ingredient name
Date of issue
Identifiers
%
67/548/EEC
Regulation (EC) No. 1272/2008 [CLP]
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Type
Notes
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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) Jotun Thinner No. 17
SECTION 3: Composition/information on ingredients Solvent naphtha (petroleum), light arom. (<0.1% Benzene)
REACH #: 01-2119455851-35 EC: 265-199-0 CAS: 64742-95-6
≥50 <75
xylene
REACH #: 01-2119488216-32 EC: 215-535-7 CAS: 1330-20-7 Index: 601-022-00-9 REACH #: 01-2119484630-38 EC: 200-751-6 CAS: 71-36-3 Index: 603-004-00-6
≥10 <25
REACH #: 01-2119489370-35 EC: 202-849-4 CAS: 100-41-4
≥3 <5
butan-1-ol
ethylbenzene
Index: 601-023-00-4
R10
Flam. Liq. 3, H226
[1] [2]
H-P
Xn; R65 Xi; R37 R66, R67 N; R51/53
STOT SE 3, H335 STOT SE 3, H336 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 Flam. Liq. 3, H226
[1] [2]
C
Acute Tox. 4, H312 Acute Tox. 4, H332 Skin Irrit. 2, H315 Flam. Liq. 3, H226
[1] [2]
-
Acute Tox. 4, H302 Skin Irrit. 2, H315 Eye Dam. 1, H318 STOT SE 3, H335 STOT SE 3, H336 Flam. Liq. 2, H225
[1] [2]
-
R10 Xn; R20/21 Xi; R38
≥10 <25
R10 Xn; R22 Xi; R41, R37/38 R67 F; R11
Xn; R20, R48/20, R65 Acute Tox. 4, H332 STOT RE 2, H373 (ears) Asp. Tox. 1, H304 See Section 16 for See Section 16 for the full text of the the full text of the H R-phrases declared statements above. declared above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment, are PBTs or vPvBs or have been assigned a workplace exposure limit and hence require reporting in this section. Type [1] Substance classified with a health or environmental hazard [2] Substance with a workplace exposure limit [3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII [4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII [5] Substance of equivalent concern Occupational exposure limits, if available, are listed in Section 8.
SECTION 4: First aid measures 4.1 Description of first aid measures General
Inhalation
Skin Eye
Ingestion Protection of first-aiders
Date of issue
: In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and seek medical advice. : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser. Do NOT use solvents or thinners. : Check for and remove any lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention. : If swallowed, seek medical advice immediately and show the container or label. Keep person warm and at rest. Do NOT induce vomiting. : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. : 23.03.2015.
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SECTION 4: First aid measures 4.2 Most important symptoms and effects, both acute and delayed Potential acute health effects Eye
: Causes serious eye damage.
Inhalation
: Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. : Causes skin irritation.
Skin Ingestion
: Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Over-exposure signs/symptoms Eye : Adverse symptoms may include the following: pain watering redness Inhalation : Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness Skin : Adverse symptoms may include the following: pain or irritation redness blistering may occur Ingestion : Adverse symptoms may include the following: stomach pains nausea or vomiting 4.3 Indication of any immediate medical attention and special treatment needed Notes to physician
: Treat symptomatically. poison treatment specialist immediately if large quantities have been ingested or inhaled. : No specific treatment.
Specific treatments
SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media
: Recommended: alcohol-resistant foam, CO₂, powders, water spray.
Unsuitable extinguishing media
: Do not use water jet.
5.2 Special hazards arising from the substance or mixture Hazards from the substance or mixture
Hazardous thermal decomposition products
: Flammable liquid and vapour. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. : Decomposition products may include the following materials: carbon dioxide carbon monoxide
5.3 Advice for firefighters Special protective actions for fire-fighters
Date of issue
: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. : 23.03.2015.
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SECTION 5: Firefighting measures Special protective equipment for fire-fighters
: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.
SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel
: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". 6.2 Environmental precautions
: Avoid dispersal of spilt material and runoff and with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage.
6.3 Methods and material for containment and cleaning up Small spill
: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product.
Large spill
6.4 Reference to other sections
: See Section 1 for emergency information. See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment information.
SECTION 7: Handling and storage The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). 7.1 Precautions for safe handling Prevent the creation of flammable or explosive concentrations of vapours in air and avoid vapour concentrations higher than the occupational exposure limits. In addition, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Mixture may charge electrostatically: always use earthing leads when transferring from one container to another. Operators should wear antistatic footwear and clothing and floors should be of the conducting type. Keep away from heat, sparks and flame. No sparking tools should be used. Avoid with skin and eyes. Avoid the inhalation of dust, particulates, spray or mist arising from the application of this mixture. Avoid inhalation of dust from sanding. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Put on appropriate personal protective equipment (see Section 8). Never use pressure to empty. Container is not a pressure vessel. Always keep in containers made from the same material as the original one. Date of issue
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SECTION 7: Handling and storage Comply with the health and safety at work laws. Do not allow to enter drains or watercourses. Information on fire and explosion protection Vapours are heavier than air and may spread along floors. Vapours may form explosive mixtures with air. When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits. 7.2 Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Notes on t storage Keep away from: oxidising agents, strong alkalis, strong acids. Additional information on storage conditions Observe label precautions. Store in a dry, cool and well-ventilated area. Keep away from heat and direct sunlight. Keep away from sources of ignition. No smoking. Prevent unauthorised access. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. 7.3 Specific end use(s) Recommendations
: Not available.
Industrial sector specific solutions
: Not available.
SECTION 8: Exposure controls/personal protection The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). 8.1 Control parameters Occupational exposure limits Product/ingredient name Solvent naphtha (petroleum), light arom. (<0. 1% Benzene) xylene
butan-1-ol
ethylbenzene
Recommended monitoring procedures
Date of issue
Exposure limit values EH40-WEL (United Kingdom (UK), 12/2011). Absorbed through skin. TWA: 200 mg/m³ 8 hours. Form: All forms TWA: 40 ppm 8 hours. Form: All forms EH40/2005 WELs (United Kingdom (UK), 12/2011). Absorbed through skin. STEL: 441 mg/m³ 15 minutes. STEL: 100 ppm 15 minutes. TWA: 220 mg/m³ 8 hours. TWA: 50 ppm 8 hours. EH40/2005 WELs (United Kingdom (UK), 12/2011). Absorbed through skin. STEL: 154 mg/m³ 15 minutes. STEL: 50 ppm 15 minutes. EH40/2005 WELs (United Kingdom (UK), 12/2011). Absorbed through skin. STEL: 552 mg/m³ 15 minutes. STEL: 125 ppm 15 minutes. TWA: 100 ppm 8 hours. TWA: 441 mg/m³ 8 hours.
: If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of procedures : 23.03.2015.
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SECTION 8: Exposure controls/personal protection for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of hazardous substances will also be required. Derived no effect levels Product/ingredient name Solvent naphtha (petroleum), light arom. (<0.1% Benzene)
Type
Exposure
DNEL Long term Dermal DNEL Long term Inhalation DNEL Long term Dermal DNEL Long term Inhalation DNEL Long term Oral
xylene
DNEL Short term Inhalation DNEL Short term Inhalation DNEL Long term Dermal DNEL Long term Inhalation DNEL Long term Dermal DNEL Long term Inhalation DNEL Long term Oral
butan-1-ol
DNEL Long term Inhalation DNEL Long term Oral DNEL Long term Inhalation DNEL Short term Inhalation DNEL Long term Dermal
ethylbenzene
DNEL Long term Inhalation DNEL Long term Inhalation DNEL Long term Oral
Value
Population
Effects
25 mg/kg Workers bw/day 150 mg/m³ Workers
Systemic
11 mg/kg bw/day 32 mg/m³
Consumers
Systemic
Consumers
Systemic
11 mg/kg Consumers bw/day 289 mg/m³ Workers
Systemic
289 mg/m³ Workers
Local
180 mg/kg Workers bw/day 77 mg/m³ Workers
Systemic
108 mg/kg Consumers bw/day 14,8 mg/m³ Consumers
Systemic
1,6 mg/kg Consumers bw/day 310 mg/m³ Workers
Systemic
3,125 mg/ kg bw/day 55 mg/m³
Consumers
Systemic
Consumers
Local
Systemic
Systemic
Systemic
Systemic
Local
293 mg/m³ Workers
Local
180 mg/kg Workers bw/day 77 mg/m³ Workers
Systemic
15 mg/m³
Consumers
Systemic
1,6 mg/kg bw/day
Consumers
Systemic
Systemic
Predicted no effect concentrations Product/ingredient name xylene
butan-1-ol
ethylbenzene
Date of issue
Type
Compartment Detail
PNEC Fresh water PNEC Marine PNEC Sewage Treatment Plant PNEC Fresh water sediment PNEC Marine water sediment PNEC Soil PNEC Fresh water PNEC Marine PNEC Sewage Treatment Plant PNEC Fresh water sediment PNEC Marine water sediment PNEC Soil PNEC Fresh water PNEC Marine PNEC Sewage Treatment
Value
Method Detail
0,327 mg/l 0,327 mg/l 6,58 mg/l
-
12,46 mg/kg dwt 12,46 mg/kg dwt 2,31 mg/kg dwt 0,082 mg/l 0,0082 mg/l 2476 mg/l
-
0,178 mg/kg dwt 0,0178 mg/kg dwt 0,015 mg/kg dwt 0,1 mg/l 0,01 mg/l 9,6 mg/l
-
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SECTION 8: Exposure controls/personal protection Plant PNEC Fresh water sediment PNEC Soil PNEC Secondary Poisoning
13,7 mg/kg dwt 2,68 mg/kg dwt 20 mg/kg
-
8.2 Exposure controls Appropriate engineering controls
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Individual protection measures Hygiene measures
Eye/face protection
: Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead.
Skin protection Hand protection
: There is no one glove material or combination of materials that will give unlimited resistance to any individual or combination of chemicals. The breakthrough time must be greater than the end use time of the product. The instructions and information provided by the glove manufacturer on use, storage, maintenance and replacement must be followed. Gloves should be replaced regularly and if there is any sign of damage to the glove material. Always ensure that gloves are free from defects and that they are stored and used correctly. The performance or effectiveness of the glove may be reduced by physical/ chemical damage and poor maintenance. Barrier creams may help to protect the exposed areas of the skin but should not be applied once exposure has occurred. May be used, gloves(breakthrough time) 4 - 8 hours: neoprene, butyl rubber, Viton®, Barricade, F 3, Responder, PVC Not recommended, gloves(breakthrough time) < 1 hour: PE Recommended, gloves(breakthrough time) > 8 hours: 4H, Teflon, nitrile rubber, polyvinyl alcohol (PVA)
Body protection
Other skin protection
Date of issue
For right choice of glove materials, with focus on chemical resistance and time of penetration, seek advice by the supplier of chemical resistant gloves. The must check that the final choice of type of glove selected for handling this product is the most appropriate and takes into the particular conditions of use, as included in the 's risk assessment. : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Refer to European Standard EN 1149 for further information on material and design requirements and test methods. : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
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SECTION 8: Exposure controls/personal protection Respiratory protection
Environmental exposure controls
: If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use respiratory mask with charcoal and dust filter when spraying this product.(as filter combination A2-P2). In confined spaces, use compressed-air or fresh-air respiratory equipment. When use of roller or brush, consider use of charcoalfilter. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance Physical state
: Liquid.
Colour Odour Odour threshold
: Clear. : Characteristic. : Not available.
pH Melting point/freezing point
: Not applicable. : Not applicable.
Initial boiling point and boiling range
: Lowest known value: 117°C (242.6°F) (butan-1-ol). Weighted average: 130. 33°C (266.6°F)
Flash point
: Closed cup: 25°C
Evaporation rate
: Highest known value: 0.84 (ethylbenzene) Weighted average: 0.65compared with butyl acetate : Not applicable.
Flammability (solid, gas) Burning time Burning rate
: Not applicable. : Not applicable.
Upper/lower flammability or explosive limits
: 1.1 - 11.3%
Vapour pressure Vapour density Relative density
: Highest known value: 1.2 kPa (9.3 mm Hg) (at 20°C) (ethylbenzene). Weighted average: 0.72 kPa (5.4 mm Hg) (at 20°C) : Highest known value: 3.7 (Air = 1) (xylene). Weighted average: 3.29 (Air = 1) : 0.86 g/cm³
Solubility(ies)
: Insoluble in the following materials: cold water and hot water.
Partition coefficient: n-octanol/ : Not available. water Auto-ignition temperature Decomposition temperature Viscosity
Explosive properties Oxidising properties
: Lowest known value: 280 to 470°C (536 to 878°F) (Solvent naphtha (petroleum), light aromatic ). : Not available. : Dynamic: Highest known value: 2.947 (butan-1-ol) Weighted average: 1.57 Kinematic: Highest known value: 0.773 cSt (ethylbenzene) Kinematic (40C): Highest known value: 0.4 to 0.9 cSt (Solvent naphtha (petroleum), light aromatic ) Weighted average: 0.65 cSt : Not available. : Not available.
9.2 Other information No additional information.
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SECTION 10: Stability and reactivity 10.1 Reactivity
: No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability
: The product is stable.
10.3 Possibility of hazardous reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
10.4 Conditions to avoid
: Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. : Reactive or incompatible with the following materials: oxidizing materials : Under normal conditions of storage and use, hazardous decomposition products should not be produced.
10.5 Incompatible materials 10.6 Hazardous decomposition products
SECTION 11: Toxicological information 11.1 Information on toxicological effects There are no data available on the mixture itself. The mixture has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. See Sections 2 and 15 for details. Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by absorption through the skin. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness. Repeated or prolonged with the mixture may cause removal of natural fat from the skin, resulting in non-allergic dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversible damage. Swallowing may cause nausea, diarrhoea, vomiting, gastro-intestinal irritation and chemical pneumonia. Aspiration hazard if swallowed. Can enter lungs and cause damage. Risk of serious damage to eyes. Product/ingredient name xylene
Result LC50 Inhalation Gas. LD50 Oral LC50 Inhalation Gas. LD50 Dermal LD50 Oral
ethylbenzene
Species Rat Rat Rabbit Rabbit Rat
Dose 6700 ppm 4300 mg/kg 4000 ppm >5000 mg/kg 3500 mg/kg
Exposure 4 hours 4 hours -
Acute toxicity estimates Route
ATE value
Oral Dermal Inhalation (vapours)
3333,3 mg/kg 5301,2 mg/kg 44 mg/l
Specific target organ toxicity (single exposure) Product/ingredient name
Category
Route of exposure
Solvent naphtha (petroleum), light arom. (<0.1% Benzene) Category 3
Not applicable.
butan-1-ol
Not applicable.
Category 3
Target organs Respiratory tract irritation and Narcotic effects Respiratory tract irritation and Narcotic effects
Specific target organ toxicity (repeated exposure) Product/ingredient name ethylbenzene
Category Category 2
Route of exposure Not determined
Target organs ears
Aspiration hazard Product/ingredient name Solvent naphtha (petroleum), light arom. (<0.1% Benzene) ethylbenzene
Date of issue
Result ASPIRATION HAZARD - Category 1 ASPIRATION HAZARD - Category 1
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SECTION 11: Toxicological information SECTION 12: Ecological information 12.1 Toxicity Product/ingredient name
Result
Solvent naphtha (petroleum), Acute EC50 <10 mg/l light arom. (<0.1% Benzene) Acute IC50 <10 mg/l Acute LC50 <10 mg/l ethylbenzene Acute EC50 7,2 mg/l Acute EC50 2,93 mg/l Acute LC50 4,2 mg/l Conclusion/Summary
Species
Exposure
Daphnia
48 hours
Algae Fish Algae Daphnia Fish
72 hours 96 hours 48 hours 48 hours 96 hours
: Water polluting material. May be harmful to the environment if released in large quantities. This material is toxic to aquatic life with long lasting effects.
12.2 Persistence and degradability Conclusion/Summary
: Not available.
Product/ingredient name
Aquatic half-life
Solvent naphtha (petroleum), light arom. (<0.1% Benzene) xylene ethylbenzene -
Photolysis
Biodegradability
-
Not readily
-
Readily Readily
12.3 Bioaccumulative potential Product/ingredient name
LogPow
BCF
Potential
Solvent naphtha (petroleum), light arom. (<0.1% Benzene) xylene butan-1-ol ethylbenzene
-
10 to 2500
high
3,12 0,88 3,15
8.1 to 25.9 -
low low low
12.4 Mobility in soil Soil/water partition coefficient (KOC)
: Not available.
Mobility
: Not available.
12.5 Results of PBT and vPvB assessment PBT
: Not applicable.
vPvB
: Not applicable.
12.6 Other adverse effects
: No known significant effects or critical hazards.
SECTION 13: Disposal considerations The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). 13.1 Waste treatment methods Do not allow to enter drains or watercourses. Material and/or container must be disposed of as hazardous waste. European waste catalogue : 08 01 11* Waste paint and varnish containing organic solvents or other dangerous substances If this product is mixed with other wastes, this code may no longer apply. (EWC) If mixed with other wastes, the appropriate code should be assigned. For further information, your local waste authority.
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SECTION 14: Transport information Transport within ’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Transport in accordance with ADR/RID, IMDG/IMO and ICAO/IATA and national regulation. International transport regulations 14.1 UN number
: 1263
14.2 UN proper shipping name
: Paint related material. Marine pollutant (Solvent naphtha (petroleum), light aromatic )
14.3 Transport hazard class(es)
: 3
Marking
: The environmental hazardous / marine pollutant mark is only applicable for packages containing more than 5 litres for liquids and 5 kg for solids. : III
14.4 Packing group 14.5 Environmental hazards
: Yes.
14.6 Special precautions for
: Transport within ’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Additional information ADR / RID
: Tunnel restriction code: (D/E) Hazard identification number: 30 Special provisions: 640E : The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.
IMDG
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Emergency schedules (EmS) F-E, S-E : Not available.
SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorisation Substances of very high concern None of the components are listed. Annex XVII - Restrictions : Not applicable. on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles Other EU regulations Europe inventory
: All components are listed or exempted.
Black List Chemicals
: Not listed
Priority List Chemicals
: Not listed
Integrated pollution prevention and control list (IPPC) - Air
: Not listed
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SECTION 15: Regulatory information Integrated pollution prevention and control list (IPPC) - Water
: Not listed
Chemical Weapons Convention List Schedule I Chemicals
: Not listed
Chemical Weapons Convention List Schedule II Chemicals
: Not listed
Chemical Weapons Convention List Schedule III Chemicals
: Not listed
15.2 Chemical Safety Assessment
: This product contains substances for which Chemical Safety Assessments are still required.
SECTION 16: Other information Indicates information that has changed from previously issued version. Abbreviations and : ATE = Acute Toxicity Estimate CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. acronyms 1272/2008] DNEL = Derived No Effect Level EUH statement = CLP-specific Hazard statement PNEC = Predicted No Effect Concentration RRN = REACH Registration Number Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] Classification
Justification
Flam. Liq. 3, H226 Skin Irrit. 2, H315 Eye Dam. 1, H318 STOT SE 3, H335 STOT SE 3, H336 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 Full text of abbreviated H statements
On basis of test data Calculation method Calculation method Calculation method Calculation method Expert judgment Calculation method : H225 H226 H302 (oral) H304 H312 (dermal) H315 H318 H332
Highly flammable liquid and vapour. Flammable liquid and vapour. Harmful if swallowed. May be fatal if swallowed and enters airways. Harmful in with skin. Causes skin irritation. Causes serious eye damage. Harmful if inhaled.
(inhalation)
Full text of classifications [CLP/GHS]
Date of issue
H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H373 May cause damage to organs through prolonged or repeated exposure. (ears) (ears) H411 Toxic to aquatic life with long lasting effects. : Acute Tox. 4, H302 ACUTE TOXICITY (oral) - Category 4 Acute Tox. 4, H312 ACUTE TOXICITY (dermal) - Category 4 Acute Tox. 4, H332 ACUTE TOXICITY (inhalation) - Category 4 Aquatic Chronic 2, H411 LONG-TERM AQUATIC HAZARD - Category 2 Asp. Tox. 1, H304 ASPIRATION HAZARD - Category 1 Eye Dam. 1, H318 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 Flam. Liq. 2, H225 FLAMMABLE LIQUIDS - Category 2 Flam. Liq. 3, H226 FLAMMABLE LIQUIDS - Category 3 Skin Irrit. 2, H315 SKIN CORROSION/IRRITATION - Category 2 STOT RE 2, H373 (ears) SPECIFIC TARGET ORGAN TOXICITY (REPEATED : 23.03.2015.
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SECTION 16: Other information STOT SE 3, H335 STOT SE 3, H336 Full text of abbreviated R phrases
Full text of classifications [DSD/DPD]
Date of printing
EXPOSURE) (ears) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
: R11- Highly flammable. R10- Flammable. R20- Harmful by inhalation. R22- Harmful if swallowed. R20/21- Harmful by inhalation and in with skin. R48/20- Harmful: danger of serious damage to health by prolonged exposure through inhalation. R65- Harmful: may cause lung damage if swallowed. R41- Risk of serious damage to eyes. R37- Irritating to respiratory system. R38- Irritating to skin. R37/38- Irritating to respiratory system and skin. R66- Repeated exposure may cause skin dryness or cracking. R67- Vapours may cause drowsiness and dizziness. R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. : F - Highly flammable Xn - Harmful Xi - Irritant N - Dangerous for the environment : 23.03.2015.
Date of issue/ Date of revision
: 23.03.2015.
Date of previous issue
: 09.12.2014.
Version
: 4.01
Notice to reader The information in this document is given to the best of Jotun's knowledge, based on laboratory testing and practical experience. Jotun's products are considered as semi-finished goods and as such, products are often used under conditions beyond Jotun's control. Jotun cannot guarantee anything but the quality of the product itself. Minor product variations may be implemented in order to comply with local requirements. Jotun reserves the right to change the given data without further notice. s should always consult Jotun for specific guidance on the general suitability of this product for their needs and specific application practices. If there is any inconsistency between different language issues of this document, the English (United Kingdom) version will prevail.
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Annex Jotun Thinner No. 17 Exposure Scenario: Uses in Coatings Sector of Use
: Industrial use
Process Category
: PROC05 PROC08a
Environmental release category(ies)
: ERC4
Industrial use
Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including product transfer and preparation, application by brush, spray by hand or similar methods) and equipment cleaning.
Operational conditions and risk management measures Control of worker exposure Frequency and duration of use
: Covers daily exposures up to 8 hours (unless stated differently)
General - Operational conditions
: Assumes use at not more than 20°C above ambient temperature, unless stated differently. Assumes a good basic standard of occupational hygiene is implemented
General - Risk management measures
: Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. Wear suitable coveralls to prevent exposure to the skin. Use suitable eye protection. See Section 8 for information on appropriate personal protective equipment.
Type of activity or process Preparation of material for application
Risk management measures : Provide a good standard of controlled ventilation (10 to 15 air changes per hour).
Control of environmental exposure Organisational measures to prevent/limit release from site
: Prevent environmental discharge consistent with regulatory requirements.
Conditions and measures related to external treatment of waste for disposal
: External treatment and disposal of waste should comply with applicable local and/or national regulations. See Section 13 for additional waste treatment information.
Conditions and measures related to external recovery of waste
: External recovery and recycling of waste should comply with applicable local and/or national regulations.
Additional information The exposure scenario for the mixture is based on the following substances: REACH #: 01-2119488216-32
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Annex Jotun Thinner No. 17 Exposure Scenario: Uses in Coatings Sector of Use
: Professional use
Process Category
: PROC05 PROC08a
Environmental release category(ies)
: ERC8a ERC8d
Professional use
Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including product transfer and preparation, application by brush, spray by hand or similar methods) and equipment cleaning.
Operational conditions and risk management measures Control of worker exposure Frequency and duration of use
: Covers daily exposures up to 8 hours (unless stated differently)
General - Operational conditions
: Assumes use at not more than 20°C above ambient temperature, unless stated differently. Assumes a good basic standard of occupational hygiene is implemented
General - Risk management measures
: Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. Wear suitable coveralls to prevent exposure to the skin. Use suitable eye protection. See Section 8 for information on appropriate personal protective equipment.
Type of activity or process
Risk management measures
Preparation of material for application Indoor
: Provide a good standard of controlled ventilation (10 to 15 air changes per hour). Avoid carrying out activities involving exposure for more than 1 hour. or Provide a good standard of controlled ventilation (10 to 15 air changes per hour). Wear a respirator conforming to EN140 with type A/P2 filter or better.
Preparation of material for application Outdoor
: Ensure operation is undertaken outdoors. Avoid carrying out activities involving exposure for more than 1 hour. or Ensure operation is undertaken outdoors. Wear a respirator conforming to EN140 with type A/P2 filter or better.
Control of environmental exposure Organisational measures to prevent/limit release from site
: Prevent environmental discharge consistent with regulatory requirements.
Conditions and measures related to external treatment of waste for disposal
: External treatment and disposal of waste should comply with applicable local and/or national regulations. See Section 13 for additional waste treatment information.
Conditions and measures related to external recovery of waste
: External recovery and recycling of waste should comply with applicable local and/or national regulations.
Additional information The exposure scenario for the mixture is based on the following substances: REACH #: 01-2119488216-32
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