Reaction Conditions For Hdo 1g3uy

Reactants Catalyst

Reaction Products Conditions

Selectivity Conver sion

Reactor

Reference

m-cresol

T= 573K, P=1 atm

Toluene, Cyclo Hexanone, 3-methyl cyclo hexanol Benzene, Phenol

28,

17

isothermal tubular reactor

Kinetics and m cresol hydrode on a Pt/SiO2 ca

7

fixed-bed quartz-tube reactor (6 mm outer diameter)

Benzene, Methane, C5-C6

63.4, 5.2, 9.1

8.8

fixed-bed reactor

Liquid- 50 ml Parr Reactor using decahydronaphthale ne (decalin, cis + trans mixture, 98% purity, SigmaAldrich) as a solvent Gas- 1/400 tubular quartz reactor micropulse reactor

Mechanistic an role of metal o the hydrodeoxygen anisole Hydrodeoxyge PhenoloverZirc edCata Effectof MetalT ReactionMech CatalystDeacti Structure, activ selectivity of b Fe/SiO2 and Pd Al2O3 catalyst conversion of f

Pt/SiO2

57, 14 80, 0

Anisole

Fe/SiO2

T= 648K, P=1 atm

Phenol

Rh/ZrO2

T= 573K, P=1 atm

furfural

bimetallic T= 523K, PdP=1 atm Fe/SiO2 H2/Feed molar ratio = 25

DeCO 16.6, products(Furan + THF), HyCO products(FOL + 83.3 MF + HFOL)

81.4

m-cresol

Two Rh/SiO2

Toluene, methylcyclohe xane, 3methylcycloh exene

30

T= 573K, P=1 atm

Controlling phe hydrodeoxygen tailoring metal eO bond streng catalyst metal particle size selection